Radioactivity is the spontaneous emission of particles or energy from an unstable atomic nucleus. This occurs in an attempt to become more stable. The nucleus loses energy by emitting radiation in the form of alpha, beta, or gamma rays.
In alpha decay, the nucleus emits an alpha particle, which consists of 2 protons and 2 neutrons. This reduces the atomic number by 2 and the mass number by 4.
Example: \(\ce{^{238}_{92}U -> ^{234}_{90}Th + ^{4}_{2}He}\)
In beta-minus decay, a neutron in the nucleus converts into a proton and emits a beta-minus particle (an electron) and an antineutrino. The atomic number increases by 1.
Example: \(\ce{^{14}_{6}C -> ^{14}_{7}N + \beta^- + \bar{\nu}_e}\)
In beta-plus decay, a proton transforms into a neutron, emitting a positron (β⁺) and a neutrino. The atomic number decreases by 1.
Example: \(\ce{^{11}_{6}C -> ^{11}_{5}B + \beta^+ + \nu_e}\)
Gamma decay often follows beta minus decay when the resulting nucleus is left in an excited state, leading to the emission of a gamma ray (high-energy photon). Gamma emission does not change the atomic number or mass number, whereas beta minus decay does. The example below will help you understand this more clearly.
Example: \(\ce{^{60}_{27}Co -> ^{60}_{28}Ni + \beta^- + \gamma}\)
In electron capture, an inner orbital electron is captured by the nucleus and combines with a proton to form a neutron. This process emits a neutrino and decreases the atomic number by 1.
Example: \(\ce{^{7}_{4}Be + e^- -> ^{7}_{3}Li + \nu_e}\)
Radioactive decay is a random process. It is not influenced by temperature, pressure, or chemical bonding. Each radioactive isotope has a fixed probability of decaying over time.
The activity (A) of a sample is the number of disintegrations per second and is measured in becquerels (Bq).
The number of undecayed nuclei N at a time t follows an exponential decay law:
\(\text{N} = \text{N}_0\:e^{-\lambda \text{t}}\)
The activity also decreases exponentially: \(\text{A} = \text{A}_0 \:e^{-\lambda \text{t}}\)
The half-life (\(\text{T}_{1/2}\)) is the time required for half of the radioactive nuclei in a sample to decay.
\(\text{T}_{1/2} = \frac{ln(2)}{\lambda} \approx \frac{0.693}{λ}\)
After each half-life, the number of undecayed atoms reduces by 50%. The half-life is constant for a given isotope.
For more information about the topics, view the topics: Types of Radioactive Decay, Properties of Radiation and Half-life and Radioactive Decay Law
Written by Thenura Dilruk